An easy and quick way to get S-Rank Armor is to repeat Chapter 5 Act 2 story mission on hard mode, when you finish that mission you will always get 1 S-Rank Armor (Orpa-Senba, Rabol-Orpad or Orpaline) which are better than the Sweet Weave obtainable at the trade mission, I got one of each attribute doing this mission over and over again, I hope this help you.
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