aside from what the others have mentioned about receptors (soul/extreme/factor), occasionally they will have items that could be potentially useful on the recycle shops. one example of this is the austere rifle being on there right now for a few more days (and at a dirt cheap price point that you can get in about 20-30 minutes). not the most interesting weapon right now, but with austere upgrades confirmed to happen in the future, that could be an awesome pickup for right now.
if you play summoner in the main game, es is awesome for leveling the pets. you can get 11* chips absurdly easy compared to high rarity eggs, and then feed those spare chips to your pet for pretty good exp.
if you play enough to be competitive in es, you can also get unique items for the main game (such as the king and queen rappy suits), which worst case scenario sell for a pretty penny if you aren't interested in keeping the costumes for yourself.
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