Np.
I'm not sure off hand how many characters there are. Well over 30, I think. You mainly take the role of Avan Harding, but while in combat you can take control of everyone you deploy. You need to build a team (there's slots for several teams you can build for specific types of missions, but I had no problems getting A ranks with only one generic team) of about 15 or 20 characters. You can only deploy 6 at any given time, but you can swap them out for anyone else on your team mid-combat. The more you play with a certain character, the friendlier they become and will eventually give you a special mission which (if you pass it) unlocks their special abilities or removes their weaknesses.
There's also codes you can put in to get access to most of the Valkyria Chronicles I characters, and if you have a save for PSP2, you can get Emilia as a partner. They don't have any special stories or dialog, but they're powerful and can be helpful early on.
Edit: Found a complete (or damned close) picture of all the characters in your squad that you can play. I don't see Aliasse there, and the teacher is only unlocked after you complete the story. But you get the idea.
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