1. Weapon Mastery? You mean the Gear skills? Those affect only that specific weapon, so you would need an all-class katana to use Katana Gear as a Fighter using a katana. Other skills will work fine whether it's from your main or sub class.
2. Yes, charged attacks only, and only on enemy weak points.
3. No, Fi/Hu is a stronger Fi/Br, and Br/Hu is a stronger Br/Fi. If you really want to use (all-class) weapons from both Fighter and Braver at the same time, then you can't do that with Hunter sub (though you can use its weapons instead!).
4. Yes, it's a good boost that's easy to use and works on bosses (unlike Chase Advance).
5. Build up your gauge by attacking enemies. Once it is full, you can block an attack with your weapon action (default Shift key) with proper timing to activate it. Once active, the gauge slowly drains (but still builds from attacks) and gives you a large damage and critrate increase. If you guard an attack when the gauge is not full, however, your gauge will be emptied without a buff.
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