Well since you asked for it, I compiled a list of what would be unarguably the greatest Photon Arts in Phantasy Star Zero. All that's left to do it pick your favorite from the list I suppose.
I love Cross Rave. Sure all the Saber Photon Arts are good, but such amazing modifiers and quick spammability with or without Compress PA (effectively leaving another Unit slot available) gives it my vote. That's the reason it made the list; Zeta Cutlass is too mobile, and Force ride leaves you vulnerable from behind for too long in my opinion.
EDIT: If a mod has the power to do this, can Bull Smash and Air Ride be added to the poll?
Kick Rush: Because I'm required to explain the awesomeness of a PA that isn't physically possible to pull off in Real Life. umad?
Cross Rave: Amazing Modifiers. The range is something to get used to, but it's much stronger and faster tha 3 Heavy Attacks, and it doesn't take long to use.
Over End: DESTROY EVERYTHING!
Bite Stamp: Once the accuracy problem is solved, this PA inflicts some serious hurt even to enemies that resist Melee attacks.
Flame Hit: A simple PA that pretty much every Hunter and Ranger needs on their Rouge Pulse. Passive Burn effect is awesome, but acuracy might be an issue.
Mine Sneak: Hard to pull off, but the modifiers make sure this PA never misses and the natural attack on the Rifle makes this PA hit incredibly hard. Some might argue that it's better or worse than Flame Hit.
Earth Bullet: An amazing range with powerful and accurate 170/150 modifiers. This is very spam-worthy. Impact Zero just doesn't match up.
Cool Style: The modifiers may only be 80/80, but a quick 30 hits come out of the Mech Guns in this PA. Aim it right and it's totally worth it. This is an amazing PA to use at Octo Diablo.
Magical Sign: This is without a doubt the greatest PA available to a Force. You stomp on things twice with your 140/160 modifiers and you Slow them in the process to size them up for the next Magical Sign. It's easily spammable in this way. Also partners up well with Gimegid in some cases.
Bright Sign: Slicers are cool, and Bright Sign is the only practical Slicer PA. You strike things three times and have a chance to Stun them in the process. It's a tad weak though . . .
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