Yes, So far, from what I've heard, I'd assume the following
-Deadlion's wand can only be obtained by breaking right arm, and unit by breaking left
-Gruzoras boots and unit are obtained by breaking its wings
-Box fists are obtained by breaking its fists.
Not 100% sure about all of them, maybe some other parts break give you other things (wondered about Ray units being tied to Anga bits). I just know those won't drop if you don't break anything.
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